我也遇到了中继访问被拒绝的问题，这真的让我很困扰。我可以从网络邮件正常发送和接收。
然而，当我在 [B]Outlook [/B] 上配置电子邮件而没有使用发送电子邮件的身份验证时，出现了以下错误：
错误：NOQUEUE：拒绝：来自未知 [MyIPaddress] 的 RCPT：554 5.7.1：中继访问被拒绝；来自= 到= proto=ESMTP helo=
如果我确实使用“我的外发服务器需要身份验证”，我会得到：
登录到接收邮件服务器 (POP3)：您的电子邮件服务器拒绝您使用安全密码验证 (SPA) 登录。在帐户设置中验证帐户属性。发送测试电子邮件消息：您的服务器不支持此客户端支持的任何验证方法。
邮件版本 = 2.6.6
主文件：
queue_directory = /var/spool/postfix
command_directory = /usr/sbin
daemon_directory = /usr/libexec/postfix
data_directory = /var/lib/postfix
mail_owner = postfix
inet_interfaces = all
# Enable IPv4, and IPv6 if supported
inet_protocols = all
mydestination = $myhostname, localhost.$mydomain, testing, testing.domain.com
unknown_local_recipient_reject_code = 550
#alias_maps = dbm:/etc/aliases
alias_maps = hash:/etc/aliases
#alias_maps = hash:/etc/aliases, nis:mail.aliases
#alias_maps = netinfo:/aliases
# The alias_database parameter specifies the alias database(s) that
# are built with "newaliases" or "sendmail -bi". This is a separate
# configuration parameter, because alias_maps (see above) may specify
# tables that are not necessarily all under control by Postfix.
#
#alias_database = dbm:/etc/aliases
#alias_database = dbm:/etc/mail/aliases
alias_database = hash:/etc/aliases
#alias_database = hash:/etc/aliases, hash:/opt/majordomo/aliases
# ADDRESS EXTENSIONS (e.g., user+foo)
#
# The recipient_delimiter parameter specifies the separator between
# user names and address extensions (user+foo). See canonical(5),
# local(8), relocated(5) and virtual(5) for the effects this has on
# aliases, canonical, virtual, relocated and .forward file lookups.
# Basically, the software tries user+foo and .forward+foo before
# trying user and .forward.
#
#recipient_delimiter = +
debug_peer_level = 2
# The debug_peer_list parameter specifies an optional list of domain
# or network patterns, /file/name patterns or type:name tables. When
# an SMTP client or server host name or address matches a pattern,
# increase the verbose logging level by the amount specified in the
# debug_peer_level parameter.
#
#debug_peer_list = 127.0.0.1
#debug_peer_list = some.domain
# The debugger_command specifies the external command that is executed
# when a Postfix daemon program is run with the -D option.
#
# Use "command .. & sleep 5" so that the debugger can attach before
# the process marches on. If you use an X-based debugger, be sure to
# set up your XAUTHORITY environment variable before starting Postfix.
#
debugger_command =
PATH=/bin:/usr/bin:/usr/local/bin:/usr/X11R6/bin
ddd $daemon_directory/$process_name $process_id & sleep 5
# If you can't use X, use this to capture the call stack when a
# daemon crashes. The result is in a file in the configuration
# directory, and is named after the process name and the process ID.
#
# debugger_command =
# PATH=/bin:/usr/bin:/usr/local/bin; export PATH; (echo cont;
# echo where) | gdb $daemon_directory/$process_name $process_id 2>&1
# >$config_directory/$process_name.$process_id.log & sleep 5
#
# Another possibility is to run gdb under a detached screen session.
# To attach to the screen sesssion, su root and run "screen -r
# <id_string>" where <id_string> uniquely matches one of the detached
# sessions (from "screen -list").
#
# debugger_command =
# PATH=/bin:/usr/bin:/sbin:/usr/sbin; export PATH; screen
# -dmS $process_name gdb $daemon_directory/$process_name
# $process_id & sleep 1
# INSTALL-TIME CONFIGURATION INFORMATION
#
# The following parameters are used when installing a new Postfix version.
#
# sendmail_path: The full pathname of the Postfix sendmail command.
# This is the Sendmail-compatible mail posting interface.
#
sendmail_path = /usr/sbin/sendmail.postfix
# newaliases_path: The full pathname of the Postfix newaliases command.
# This is the Sendmail-compatible command to build alias databases.
#
newaliases_path = /usr/bin/newaliases.postfix
# mailq_path: The full pathname of the Postfix mailq command. This
# is the Sendmail-compatible mail queue listing command.
#
mailq_path = /usr/bin/mailq.postfix
# setgid_group: The group for mail submission and queue management
# commands. This must be a group name with a numerical group ID that
# is not shared with other accounts, not even with the Postfix account.
#
setgid_group = postdrop
# html_directory: The location of the Postfix HTML documentation.
#
html_directory = no
# manpage_directory: The location of the Postfix on-line manual pages.
#
manpage_directory = /usr/share/man
# sample_directory: The location of the Postfix sample configuration files.
# This parameter is obsolete as of Postfix 2.1.
#
sample_directory = /usr/share/doc/postfix-2.6.6/samples
# readme_directory: The location of the Postfix README files.
#
readme_directory = /usr/share/doc/postfix-2.6.6/README_FILES
virtual_alias_maps = hash:/etc/postfix/virtual
sender_bcc_maps = hash:/etc/postfix/bcc
mailbox_command = /usr/bin/procmail-wrapper -o -a $DOMAIN -d $LOGNAME
home_mailbox = Maildir/
smtpd_sasl_auth_enable = yes
smtpd_sasl_security_options = noanonymous
broken_sasl_auth_clients = yes
#smtpd_recipient_restrictions = permit_mynetworks permit_sasl_authenticated reject_unauth_destination
smtpd_relay_restrictions = permit_mynetworks, permit_sasl_authenticated, defer_unauth_destination
mailbox_size_limit = 0
allow_percent_hack = no
非常感谢您的帮助。