使用 chemfig 对堆叠分子进行中心对齐

Question

右侧，从乙烯到的垂直箭头M是配位键。是否可以将两个分子（乙烯和固体催化剂表面）居中对齐，使它们的中心与配位键箭头对齐？

\documentclass[12pt]{article}

\usepackage{tikz}
\usetikzlibrary{arrows.meta}
\usepackage{chemfig}
  
\usetikzlibrary{shapes,positioning,intersections,quotes}    


\setchemfig{%
        arrow offset=9pt,
        arrow coeff=0.7,
        + sep left=0.3em,
        + sep right=0.3em,
        atom sep=1.5em,
        fixed length=true
}

\begin{document}
\schemestart
\chemfig{C(-[3]H)(-[5]H)=C(-[1]H)-[7]H}
\arrow{0}[,0] \+
\chemfig{ M (-[0]M{\sim}) (-[4]{\sim}M) }
\arrow
\subscheme{
    \chemfig{H_2C=[@{bond}]CH_2}
    \arrow{0}[-90,.23]
    \chemfig{ M (-[0]M{\sim}) (-[4]{\sim}M) }
    \chemmove{
        \node[below=3px of bond] (double_bond) {};
        \node[below=19px of bond] (solid_surface) {};
        \draw[-stealth](double_bond)--(solid_surface);
    }
}
\schemestop
\end{document}

Answer 1

问题是 后面有一个你不想要的空格\chemfig{ M(-[0]M{\sim}) (-[4]{\sim}M) }。添加%以删除行末的空格。

\subscheme{
    \chemfig{H_2C=[@{bond}]CH_2}
    \arrow{0}[-90,.23]
    \chemfig{ M(-[0]M{\sim}) (-[4]{\sim}M) }% <--------NEED THIS!!
    \chemmove{
        \node[below=3px of bond] (double_bond) {};
        \node[below=19px of bond] (solid_surface) {};
        \draw[-stealth](double_bond)--(solid_surface);
    }
}
\schemestop

Answer 2

没有必要使用 \subscheme 或 \chemmove，可以使用更短的代码。无需使用 \arrow 命令即可将箭头插入分子内部

    \documentclass[12pt]{article}
    \usepackage{tikz}
    \usetikzlibrary{arrows.meta}
    \usepackage{chemfig}

\usetikzlibrary{shapes,positioning,intersections,quotes}    


\setchemfig{%
    arrow offset=9pt,
    arrow coeff=0.7,
    + sep left=0.3em,
    + sep right=0.3em,
    atom sep=1.5em,
    fixed length=true
}


\begin{document}
\schemestart
    \chemfig{C(-[3]H)(-[5]H)=C(-[1]H)-[7]H}
    \arrow{0}[,0] \+
    \chemfig{ M(-[0]M{\sim})(-[4]{\sim}M)}
    \arrow
\chemfig{H_2C=[,.5](-[6,,,,->,shorten <=2pt]M(-[0]M{\sim})(-[4]{\sim}M))=[,.5]CH_2}
\schemestop
\end{document}